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二元中性体系对金(Ⅲ)的协同萃取研究 Ⅱ.TBP+DPSO的苯溶液协萃金(Ⅲ)及其机理
STUDIES ON SYNERGIC EXTRACTION OF GOLD(Ⅲ) BY BINARY NEUTRAL SYSTEM (Ⅱ) SYNERGIC EXTRACTION OF GOLD(Ⅲ) WITH TBP AND DPSO IN BENZENE SOLUTION AND ITS MECHANISM
【摘要】 本文研究磷酸三丁酯(TBP)与二苯基亚砜(DPSO)组成的二元中性体系(B-B体系)在HCl介质中对金(Ⅲ)的萃取行为,发现该体系有明显的协同萃取效应。用斜率法和紫外光谱法确定了协萃配合物的组成为H3O+·2TBP·DPSO·yH2O……AuCl4-·HCl。协萃反应的平衡常数log K1,2′=3.33。对协萃反应的机理和可能的结构也进行了讨论。
【Abstract】 The synergic extraction of gold( Ⅲ ) from hydrochloric acid medium with mixtures of tributyl phosphate(TBP) and diphenyl sulfoxide(DPSO) in benzene has been investigated.The formation of the extracted species H3O+·2TBP·DPSO ·yH2O…AuCl4-·HCl is confirmed by slope analysis and UV spectra. The equilibrium constant of the extraction reaction log K1,2 = 3.33 is calculated.
【基金】 中国科学院科学基金资助的课题
- 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,1987年04期
- 【被引频次】1
- 【下载频次】39