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铜(Ⅱ)离子影响下酚醚的裂解
CLEAVAGE OF PHENOLIC ETHER UNDER INFLUENCE OF Cu(I) ION
【摘要】 4-氯-2-(对-硝基苯甲氧基)-1,3-苯二甲醛和邻-氨基苯酚生成的双Schiff碱在乙醇溶液中和水合醋酸铜反应,在Cu(Ⅱ)离子的影响下醚链裂解,生成双核配合物和对-硝基苄醇。
【Abstract】 The bis-Schiff base prepared from 4-chloro-2-(p-nitro-benzyloxy ) isophthalaldehyde and o-aminophenol was treated with cupric acetate monohydrate in absolute alcohol. The ether linkage was cleaved under the influence of Cu( Ⅱ ) ion and the products isolated were a copper( Ⅱ ) binuclear complex and p-nitrobenzyl alcohol.
【关键词】 裂解;
酚醚;
双Schiff碱;
Cu(Ⅱ)双核配合物;
【Key words】 cleavage phenolic ether bis-Schiff base copper( Ⅱ ) binuclear coordination compound;
【Key words】 cleavage phenolic ether bis-Schiff base copper( Ⅱ ) binuclear coordination compound;
- 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,1987年02期
- 【被引频次】1
- 【下载频次】52