【摘要】 在二氯甲烷中氩气保护下用氧化碘苯氧化ClMn^ⅢT（P—R）PP,其中R=-OCH₃或-CO₂CH₃,合成了氧络锰（Ⅳ）卟啉配合物,O=Mn^ⅣT（P—R）PP。它们的可见吸收光谱在波长为430nm处有强的Soret带和525nm处有宽的肩吸收带。红外光谱在波数为1060cm^-1处有Mn=O的特征吸收峰。它们具有氧化碳氢化合物的性质。更多还原

【Abstract】 Oxo manganese ( IV ) porphyrin complexes, O= MnIV T ( P-R ) PP, R=-OCH3or -CQ2CH3, were synthesized from the oxidation of CIMn Ⅲ T(P-R)PP in dichloromethane under Ar using iodosylbenzene. Their visible absorption spectra show an intense Soret band at 430 nm and a broad shoulder band at 525 nm. The infrared spectra show an absorption band at 1060 cm-1. It is assigned to a Mn = O stretch. They have the properties of oxidizing hydrocarbons.更多还原