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酸碱滴定和氧化还原滴定中准确滴定条件的探讨
THE APPROACH OF PREREQUISITE FOR EXACT TITRATION IN THE ACID-BASE TITRATION AND OXIDATION-REDUCTION TITRATION
【摘要】 本文根据滴定分析的误差要求,以滴定曲线突跃范围为依据,对酸碱滴定和氧化还原滴定中,能准确滴定的条件进行了探讨。提出弱酸(碱)滴定的条件为CK≥10-8;多元酸(碱)分步滴定的条件为Ka1Ka2≥105,氧化还原滴定的条件为E10′-E20′≥0.56伏,并相应进行了有关公式的推导。
【Abstract】 On ask for errors of analysis by titratior, to be based on transitory range of titration curve, go about approach of prerequisite for exact titration in the acid-base titration and oxidation-reduction titration. Put forward prereguisite for exact titration in the weak acid (or base) is CK≥-8, prereqnisite for stepwise titration in the poljhydric acid (or base) is Ka1/Ka2≥10-5, in the oxidation-reduction is E10-E20≥0.56V. In the meantime go about deduction of these formua.
【关键词】 酸碱滴定;
氧化还原滴定;
滴定条件;
【Key words】 Acid-baset itration; oxidation-reduction titration; prerequisite for titration;
【Key words】 Acid-baset itration; oxidation-reduction titration; prerequisite for titration;
- 【文献出处】 山东建材学院学报 ,Journal of Shandong Institute of Building Materials , 编辑部邮箱 ,1987年03期
- 【被引频次】1
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