【摘要】 合成了一系列新的二茂铁在侧基、端基和嵌入主链三种类型的聚硅烷,测定了它们的虹外,紫外可见光谱,分子量和电阻率;讨论了二茂铁在聚硅烷的不同位置上对聚硅烷紫外光谱和导电性的影响。同时,测定了聚硅烷与某些电子受体形成CT络合物的紫外可见光谱和导电性,聚硅烷与某些电子受体络合可显著提高导电性。更多还原

【Abstract】 A new series of polysilanes containing ferrocene has been synthesized.Their IR,UV,molecular weights and specific resistance have been measured.The influence of ferrocene located in different places on UV and conductivity of polysilanes has been discussed.Furthermore,we have measured UV and conductivity of charge-transfer conplexes formed fromthe polysilanes and some electronic acceptors.The conductivity of complexes is much higher than that of the polysilanes.更多还原