【摘要】 以 S—甲基—β—N—(0—羟苯基乙叉)-二硫代肼基甲酸盐为配体,合成了钴(Ⅲ)和铁(Ⅲ)的配合物。测定了它们的化学组成、电导、磁化率、差热—热重、紫外——可见光谱以及红外和远红外光谱,初步提出了配合物的结构并测定了它们的杀菌活性,发观它们是十分有效的。更多还原

【Abstract】 The present paper describes the synthesis and structural features of cobalt （Ⅲ）and iron（Ⅲ）complexes with S-methyl-β-N-（0-hydroxyphenylethylidene） -dithiocarbazate.The resulting complexes of the type,CoL₂ and FeL₂,have been characterized on the basis of elemental analyses,molar conductance,DTA, TG,UV—visible and IR spectroscopic measurement.In has been found that they have octahedral geometries.In addtion,the complexes and the ligand have been tested against bacteria（B.Subtilis and E.C Ii）and found to be quite active.更多还原