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电位分析中二次标准加入法的计算机逼近
Computer Approach to the two Standard Addition Method in Potentiometric Analysis
【摘要】 Brand等作者认为,以S=RT/nF为初值时,迭代法得不到未知浓度C0的收敛解。本文理论分析证明,以不同初值(S=RT/nF或C0)的迭代法的收敛性和发散性具有一定的客观规律性。进而又成功地计算了氯、钙和铬离子等实例。计算结果与现有资料中的电算结果完全相符。
【Abstract】 Brand et. al. consider that it is does not lead to convergence of anunknown concentration C0 when the iteration method is to put S=RT/nF. Theoretical analysis of this paper shows that convergence anddivergence of the method with different initial values (S=RT/nF or C0)have definite objective laws, and then it is successfully used tocalculate the concentrations of chloride calcium and lead cations. Theresults are completly consistent with those obtained by computer incurrent literature.
- 【文献出处】 计算机与应用化学 ,Computers and Applied Chemistry , 编辑部邮箱 ,1987年02期
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