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常温复分解法制备碳酸锶的实验研究

EXPERIMENTAL STUDY ON SrCO3 PREPARATION BY DOUBLE DECOMPOSITION AT ROOM TEMPERATURE

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【作者】 刘鹏先; 雷贞桂;

【Author】 Liu Pengxian Department of General Chemistry Lei Zhengui The Fifth Chengdu Pharmaceutical Factory

【机构】 华西医大普通化学教究室; 成都制药五厂;

【摘要】 作者根据化学热力学原理证明碳酸铵与天青石的复分解反应可在常温下进行。矿粉经除钙、复分解转化除钡,除铁、沉淀、洗涤等,制得符合出口标准的碳酸锶产品。本工艺有节能、降低成本及设备投资等优点。

【Abstract】 Powdered celestite was mixed withsolution of calcium-removing agent,stirredand filtered, and then the precipitate waswashed and mixed with(NH4)2CO3 solutionat room temperature for transformation.The precipitate was filtered and washed toobtain crude SrCO3, which was thendissolved in 6N HCl and filtered at pH6-7 to remove Fe. The filtrate was mixedwith a saturated solution of (NH4)2CO3 or(NH4)HCO3 at pH 9 and filtered, and theprecipitate was washed and dried to obtainpure SrCO3.

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