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大气中的硝酸及其相关因素

NITRIC ACID IN THE ATMOSPHERE OVER BEIJING AREA

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【作者】 孙庆瑞王美蓉邵可声白玉华董国强黄腾

【Author】 Sun Qingrui, Wang Meirong, Shao KeshengBai Yuhua, Dong Guoqiang, Huang Teng (Dept. of Technical Physics, Peking University)

【机构】 北京大学技术物理系北京大学技术物理系

【摘要】 采集了173个大气样品,测定其HNO3含量,同时测定了O3、NO2、NH3、t、RH,并对数据进行了多元逐步回归处理。结果表明,O3与HNO3相关最好。与HNO3呈正相关的是O3、NO2、t;呈负相关的是NH3、RH。通过HNO3、NH3的浓度,计算了平衡常数,证明在低湿度下大气中存在固态NH4NO3与气态HNO3、NH3的平衡。

【Abstract】 The concentrations of HNO3, NO2, O3, and NH3 in 173 samples collected during 1984, 12-1986,7 were determined and the data were then analyzed using multiple regression method. The results indicated that HNO3 concentration is significantly correlated to O3 concentration. In addition, HNO3 concentration increases with the increases in temperature and O3 concentration and decreases with the increases in relative humidity and NH3 concentration. Under low relative humidity condition, HNO3 (g) and NH3 (g) reach equilibrium with NH4NO3 (s) in the atmosphere.

【关键词】 硝酸臭氧
【Key words】 air pollutionnitric acidozone.
  • 【文献出处】 环境科学学报 ,Acta Scientiae Circumstantiae , 编辑部邮箱 ,1987年04期
  • 【被引频次】4
  • 【下载频次】80
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