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SO42-/ZrO2固体超强酸酸性和烯烃烷基化催化性能之间的关系

Study of the Relationship Between Acidity of SO42-/ZrO2 Solid Superacid and Its Catalytic Activity in Olefin Alkylation

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【作者】 崔圣范王江张松盛温陵生孙中琦千载虎

【Author】 Cui Shengfan, Wang Jiang, Zhang Songsheng, Wen Lingsheng, Sun Zhongqi and Qian Zaihu(Department of Chemistry, Jilin University, Changchun)

【机构】 吉林大学化学系吉林大学化学系

【摘要】 本文研完了SO42-/ZrO2型固体超强酸酸性和烯烃烷基化催化性能之间的关系。得到了B酸量和L酸量之比(B/L)与酸强度、活性、选择性之间的相关性。当B/L值趋于2时,表现出最高的酸强度和最佳的催化活性与选择性。

【Abstract】 This paper reports the relationship between the acidity of SO42-/ZrO2 type solid superacid and its catalytic activity in olefin alkylation, and the correlation of the acidity, activity and selectivity of the superacid as a catalyst with the ratio of the quantity of Bronsted acid site to that of Lewis acid site (B/L) on it is observed. As the value of B/L approaches to 2, it shows the highest acid strength and the optimum catalytic activity and selectivity.

  • 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,1987年06期
  • 【被引频次】8
  • 【下载频次】77
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