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强脉冲激光激发的热透镜光度分析法

Thermal Lens Spectrophotometry Based on Strong Pulsed Laser Excitation

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【作者】 邓延倬曹建文刘村陈观铨曾云鹗

【Author】 Deng Yanzhuo, Cao Jianwen, Liu Cun and Chen Guanquan (Centre of Analysis and Testing, Wuhan University, Wuhan)Zeng Yun’e (Department of Chemistry, Wuhan University, Wuhan)

【机构】 武汉大学分析测试中心武汉大学化学系

【摘要】 用自装的热透镜测量装置,观察了强脉冲激光作用下的热透镜行为。测量丙酮/水混合液中的Cocl2,检测限为3×10-7M,相当于6×10-6的吸光度。将差分放大技术用于热透镜测量,降低了He-Ne激光振幅噪声的影响,改善了信噪比。

【Abstract】 The thermal lens effects based on the strong pulsed laser excitation were observed by using the home-made experimental apparatus. In acetone-water mixture concentrations of CoCl2 as low as 3×10-7M have been determined with present setup, which corresponds to an absorbance of 6×10-6. In thermal lens measurements the noise level due to shot-term instability of the He-Ne laser output amplitude can be reduced down by the use of differential amplification technique, thus the S/N ratio is improved appreciably.

【基金】 中国科学院科学基金
  • 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,1987年06期
  • 【被引频次】7
  • 【下载频次】21
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