【摘要】 <正> N-烃基邻苯二甲酰亚胺类化合物是合成脂肪族伯胺和α-氨基酸的重要中间体。近年来,Landini,D.,Santaniallo,E.等先后报道过在鎓盐存在下进行邻苯二甲酰亚胺的相转移催化烃化反应。 聚乙二醇(PEG)是一类新的很有发展前途的相转移催化剂,被认为是相转移催化反应中理想的冠醚替代物。水文报道了PEG在邻苯二甲酰亚胺N-烃化反应中的相转更多还原

【Abstract】 This paper reports the synthesis of N-alkyl derivatives of phthalimides by using polyethylene glycols(PEG) as phase transfer catalysts. Thirteen N-alkyl phthalimides were obtained by the phase transfer catalytic reactions of phthalimides with corresponding alkyl halides in the presence of absolute potassium carbonate and PEG-400.更多还原