【摘要】 <正> 文献报导二苯基N-无取代硫亚胺(Ⅰ)和醛作用可得对应的腈,曾设想其机理如下 已知苄叉氯亚胺可分解成相应的腈,考虑到它在结构上与瞬时中间体B相似,如果在二苯硫醚共存下反应,可能形成结构上与B很相似的C。更多还原

【Abstract】 This paper reports a simple preparative method of benzalchloroimine-1-d. The kinetic study on the reaction of benzalchloroimine Ia-b with diphenyl sulfide in benzene has been carried out. From, p value of Hammett equation and the kinetic isotope effect, its mechanism of reaction was tendered.更多还原