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pH 电位滴定法测定二元酸稳定常数 Ⅰ.样条插值——计算法和 Rossotti 图解法

DETERMINATION OF STABILITY CONSTANTS OF BINARY ACIDS USING pH POTENTIAL TITRATION METHOD Ⅰ.SPLINE INTERPOLATION-CALCULATION METHOD AND ROSSOTTI GRAPHICAL METHOD

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【作者】 聂圣哲周拴虎戴维列胡闻天

【Author】 Nie Shengzhe Zhou Shuanhu (Department of Chemistry,Anhui University)Dai Weilie (Department of Chemistry,Zhongshan University)Hu Wentian (Department of Chemistry,Sichuan University)

【机构】 安徽大学化学系中山大学化学系四川大学化学系 合肥合肥广州成都

【摘要】 <正> 本文利用样条插值,通过计算法和Rossotti图解法对新合成的N,N-二羧甲基对甲苯磺酞胺的稳定常数进行了测定。同时,我们还对样条拟合进行了探索。针对方法的要求,自编程序,用计算机处理数据。实验部分 1.溶液的配制和标定 NaOH标准溶液:CB=0.0954M(0.1M KCl介质);N,N-二羧甲基对甲苯磺酞胺溶液:COL=3.600×10-2M;0.4M KCl溶液,作为0.1M KCl介质补偿液。

【Abstract】 The Spline Interpolation-Calculation Method and Rossotti Graphical Method have been applied to determine the stability constant of the newly synthesized N, N-dicarboxylic me-thyl-p-toluene sulfamide. Meanwhile, the fitting of Spline was investigated. A suitable calculation process for this method was programmed. And a series of processing of inter-polations, judgements, calculations and graph drawings were completed with computer.

  • 【文献出处】 分析化学 ,Chinese Journal of Analytical Chemistry , 编辑部邮箱 ,1987年05期
  • 【被引频次】2
  • 【下载频次】91
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