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γ-Fe2O3磁粉的表面特性

THE SURFACE CHARACTERISTICS OF γ-Fe2O3 POWDER

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【作者】 金士九; 顾菊瑛; 成林; 周祖康;

【Author】 Jin Shijiu;Gu Juying;Cheng Lin;Zhou Zukang Institute of Chemistry, Academia Sinica Department of Chemistry, Beijing University

【机构】 中国科学院化学研究所; 北京大学化学系;

【摘要】 要提高磁带、磁盘等磁记录材料的记录密度,“分散”问题是关键之一,而分散过程中的润湿、磁粉团的解体和粒子的凝聚都直接与磁粉的表面特性有关。本文通过各种极性或非极性液体对密堆积磁粉的渗透速度以及磁粉在这些液体中沉降体积测定,研究了液体对磁粉的润湿特性,估测了它们的接触角;文内还尝试按Fowkes理论假定进行了计算,求得γ-Fe2O3磁粉表面张力为:γsd=24dyn/cm,γsp=17dyn/cm,γs=γsd+γsp=41dyn/cm。

【Abstract】 Dispersion of γ-Fe2O3 powder in polymer solution plays an important role in gover-ning the recording density of magnetic recording materials. The wetting of the powders,disintegration of agglomerates and agglutination of particles are closely related to the surfacecharacteristics of γ-Fe2O3 powder. In this paper, the wetting characteristics and the appa-rent contact angles of γ-Fe2O3 powder in polar and non-polar liquids were estimated bydetermining the penetration rates of these liquids through powders, as well as the sedimen-tative volume of powders in liquids. Based on Fowkes’ theoretical assumption,the valuesof the surface tension of γ-Fe2O3 powder were calculated: γsd= 24 dyn/cm,γsp=17dyn/cmand γs=41dyn/cm.

  • 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,1986年03期
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