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卢氏香茶菜乙素的结构
STRUCTURE OF LUDONGNIN B
【摘要】 从卢氏香茶菜叶的乙醚提取物中分得一个新的二萜化合物,卢氏香茶菜乙素(ludongnin B),其结构经各项光谱数据确定为(1)式。
【Abstract】 Rabdosia rubescens Hara var. lushiensis Gao et Li(Labiatae) which is widely distributed in the Funiushan west area of Henan, has been used for the treatment of esphagel and cardial carcinoma in Henan, We have reported the isolation and the structural determination of ludongnin A from the ethereal extract of the dry leaves of this plant. The present paper, we report studies on a new crystalline diterpenoid, ludongnin B [C20H28O5, mp 296-9 ℃] which is a minor component isolated from the same plant and its structure has been shown to be ent- 6 , 7 -spiroseco- 7 , 20-δ -lactonic ring-6, 19- γ -lactonic ring-16-kaurane-15-one ( 1 ) on the basis of spectroscopic evidence and compared with known compound, ludongnin A.
【Key words】 Diterpenoid; ent-kaurane; Rabdosia rubescens var. lushiensis ludongnin B, Structure; 1H NMR, 13C NMR;
- 【文献出处】 云南植物研究 ,Acta Botanica Yunnanica , 编辑部邮箱 ,1986年02期
- 【被引频次】15
- 【下载频次】60