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铁的碳酸盐矿物的选择溶解

The Selective Dissolution of Ferro-Carbonate Minerals

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【作者】 王忠贤;

【Author】 Wang Zhongxian(Zhengzhou Institute of Complex Utilization of Mineral Resources, Ministry of Geology and Mineral Resources)

【机构】 地矿部郑州矿产综合利用研究所;

【摘要】 <正>铁的碳酸盐矿物主要指菱铁矿(FeCO3)由于FeCO3与MnCO3和MgCO3能形成完全类质同象系列;与CaCO3形成不完全类质同象系列,所以菱铁矿中经常含有Mn、Mg、Ca类质同象混入物,形成变种:锰菱铁矿,镁菱铁矿,钙菱铁矿以及含铁的锰镁碳酸盐矿。其次是指由于CaMg[CO3]2(白云石)~CaFe[CO3]2形成完全类质同象系列的镁铁白云石[CaCO3·(Mg·Fe)CO3],当Fe>Mg时称铁白云石。

【Abstract】 The advance of solvents for selective dissolution of ferro-carbonate minerals is discribed in this paper. Investigation showed that three solutions, 10%A1C13 · 6H2O, 10%A1C13 · 6H2O-0.5% NaHCO3 and 30% NH4C1-0.25% 1,10 phenanthroline, are proper. The dissolutions of siderite, sid-erodot and ankerite are over 97% completely. These solvents dissolve chlorite less than 6%, and greenalite, biotite, amphibole and garnet less than 2%. Hematite, lirnonite, specularite, magnetite and pyrite are hardly dissolved. The selectivity of the three solvents is good, and the procedures are simple with satisfactory results.

  • 【文献出处】 冶金分析 ,Metallurgical Analysis , 编辑部邮箱 ,1986年04期
  • 【被引频次】3
  • 【下载频次】99
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