【摘要】 R_3i—D_4d—C_2v是一条群链。本文讨论如何应用D_4d群的标准基函作为C_2v群的基函来写出d^N体系在C_2v对称性场中各配场谱项的能量矩阵H₁。H₁中的H_el。部分完全可以应用D_4d的H₁中的H_el。,因而简化了计算。所得能量矩阵H₁与前文列出的H₁等价。更多还原

【Abstract】 R3i-D4d-C2o is a group chain. In this paper we use the standard basis functions of D4d group as the basis functions of C2u group to calculate the energy matrices H1 of the terms of dN system in ligand field of C2v symmetry. The Hel. part in H1 of C2v symmetry can use the He1. part in H1 of D4d symmetry and thus simplifies the calculations. Energy matrices thus obtained are equivalent to those listed in a previous paper[5].更多还原