【摘要】 研究了以烷基铝与异戊醚形成的络合物还原TiCl₄的还原历程,得到了还原曲线。Ti⁺³含量的实测值比按通常Solvay催化剂的理论计算值高一倍。证明了这是反应副产物AlEtCl₂进一步还原TiCl₄的结果.另外,对异戊醚、正丁醚、苄基醚含氧化合物,以及吡啶、吡咯啉含氮化合物等作为催化剂第三组份也进行了研究。更多还原

【Abstract】 The process of reduction of titanium tetrachloride with alkyl aluminiumdiisoamyl ether complex was studied. The reduction curves were obtained. The centent of Ti⁺³ was found to be twice as high as the calculated value. These proved that titanium tetrachloride was further reduced by the reactive by-product AlEtCl₂.更多还原