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N-(β-胺基-4-氯桂皮酰基)另丁胺类化合物的NMR及构型研究

THE NMR AND CONFIGURATION STUDY OF N-(P-SUBSTITUTED AMINO -4-CHLORCINNAMYL) -SEC-BUTYLAMINES

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【作者】 彭师奇刘维勤张爱军陈素明千金子

【Author】 Peng Shiqi Liu Weiqin Chen Suming Zhang Aijun and Qian Jinzi(College of Pharmaceutical Sciences Beijing Medical University,Bei jing)

【机构】 北京医科大学药学院中国科学院化学研究所中国科学院物理研究所

【摘要】 本文报道了一类新化合物N-(β-胺基-4-氯桂皮酰基)另丁胺的NMR及烯胺结构中氮上质子与相邻碳上质子间的偶合。依据~1HNMR指定了这类化合物的构型,提出了一个化合物的X光衍射结果,证实了所指定的构型,用去偶技术确认了烯胺结构中氮上质子与相邻碳上质子间的偶合现象。

【Abstract】 In this paper the NMR and the coupling of pnotons on the nitrogen atom and its neighbouring carbon atom in N-(3-substituted amino-4-chIorocinnamyl) -sec-butylamines, a kind of new compounds, were reported.The configurations of these compounds were assigned based on their 1N-NMR, and confinmed by the X-ray diffraction results of one of these coznpounds.The coupling phenomenon of protons on the nitrogen and its neighbouring carbon in these compounds was confirmed by decoupling technique

  • 【文献出处】 波谱学杂志 ,Chinese Journal of Magnetic Resonance , 编辑部邮箱 ,1986年04期
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