【摘要】 从S-苄基二硫代肼基甲酸酯（H₂NNHCSSCH₂C₆H₅）衍生出的两种希夫碱——邻氯苯甲醛希夫碱O—CIC₆H₄CHNNHC（S）SCH₂C₆H₅和亚苄基丙酮希夫碱C₆H₅CHCHC（CH₃）NNHC（S）SCH₂C₆H₅为配体,合成了与镍和铜的四种新的螯合物。对这些配合物进行了化学分析以及电导,磁性、紫外-可见光谱和红外光谱等性质的研究。结果表明,Ni（Ⅱ）与上述两种配体形成具有[NiA₂]和[NiB₂]形式的反磁性的平面正方形配合物,其中配体为单价双齿阴离子配体。Cu（Ⅱ）与邻氯苯甲醛希夫碱形成反磁性的Cu（Ⅰ）配合物[Cu（HA）A]。Cu（Ⅱ）与亚苄基丙酮希夫碱形成室温下磁矩为1.44B.M.的双核配合物[Cu₂Cl₂B₂],其中每个Cl桥与两个Cu（Ⅱ）相连,每个Cu（Ⅱ）具有平面正方形的配位结构。更多还原

【Abstract】 The coordination compounds of copper and nickel with Schiff bases OC1C₆H₄ CHNNHC（S）S CH₂C₆H₅（HA） and C₆H₅CH=CHC（CH₃）NNHC（S） SCH₂C₆H₅（HB）, derived from S-benzyldithiocarbazate, have dean prepared and characterized by elemental analyses, molar conductances, magnetic susceptibility, IR and UY-visible spectroscopy and thermostability. Based on the properties examined,the compositions of [NiA₂],[NiB₂] [Cu（H A）A]and(Cu₂Cl₂B₂]are formed.The first three of the compounds are diamagnetic, the last one having 1.44 B.M.is a dinuclear complex,in which the two Cu atoms are each bridged by two Cl atoms.更多还原