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钙电极法和pH滴定法测定牙科偶联剂NBG-GMA与钙离子络合稳定常数

DETERMINATION OF THE STABILITY CONSTANT OF NBG-GMA CALCIUM COMPLEX BY CALCIUM ION-SELECTIVE ELECTRODE AND pH-TITRATION METHODS

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【作者】 邹肇娥陈洪超雷厚成郭明秀

【Author】 Zou Shao-E Chen Hong-Chao Lei Huo-Chen Guo Ming-Xiu (West China University of Medical Sciences, Chingdu)

【机构】 华西医科大学基础医学系有机化学教研室华西医科大学基础医学系普通化学教研室华西医科大学基础医学系普通化学教研室 成都成都

【摘要】 作者采用pH滴定法和钙电极法测定自制新化合物NBG—GMA与钙离子的络合稳定常数。用pH滴定法测得Igk稳平均值为8.95(20℃)。用作者自己推演的计算公式的钙电极法测得的Igk稳平均值为8.72(25℃)。

【Abstract】 The new dental coupling agent NBG-GMA was synthesized, and the adhcsive strength between dentine and resin was improved. So the stability constant of NBG-GMA calcium complex was determined by pH-titration and calciuim-sensitive electrode methods. The lgkstab measured by the former method was 8.95 at 20℃ in 95% alc, soln. But that measured by the later method was 8.72 at an ion strength of 0.1M NaCl and 25℃ in 50% alc. soln., An equation was deduced for the calculation of lgkstab in the calcium ion-selective electrode measurement.

  • 【文献出处】 华西药学杂志 ,West China JOurnal of Pharmaceutical Sciences , 编辑部邮箱 ,1986年02期
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