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钙电极法和pH滴定法测定牙科偶联剂NBG-GMA与钙离子络合稳定常数
DETERMINATION OF THE STABILITY CONSTANT OF NBG-GMA CALCIUM COMPLEX BY CALCIUM ION-SELECTIVE ELECTRODE AND pH-TITRATION METHODS
【摘要】 作者采用pH滴定法和钙电极法测定自制新化合物NBG—GMA与钙离子的络合稳定常数。用pH滴定法测得Igk稳平均值为8.95(20℃)。用作者自己推演的计算公式的钙电极法测得的Igk稳平均值为8.72(25℃)。
【Abstract】 The new dental coupling agent NBG-GMA was synthesized, and the adhcsive strength between dentine and resin was improved. So the stability constant of NBG-GMA calcium complex was determined by pH-titration and calciuim-sensitive electrode methods. The lgkstab measured by the former method was 8.95 at 20℃ in 95% alc, soln. But that measured by the later method was 8.72 at an ion strength of 0.1M NaCl and 25℃ in 50% alc. soln., An equation was deduced for the calculation of lgkstab in the calcium ion-selective electrode measurement.
- 【文献出处】 华西药学杂志 ,West China JOurnal of Pharmaceutical Sciences , 编辑部邮箱 ,1986年02期
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