【摘要】 <正> Park等从全氟丙烯与三氯化铝的反应产物中,分离出一系列氟氯烯烃,并指出该反应中全氟丙烯氟原子被氯原子取代的次序.CF₂ClCFClCF₂CFCl₂（1）与三氯化铝反应,仅得到CF₂ClCFClCF₂CCl₃,产率58％.我们研究了1及CFCl₂CF₂CFCl₂（2）分别与三氯化铝的反应.由1的反应得CF_更多还原

【Abstract】 Aluminum chloride reacted with CF₂ClCFClCF₂CFCl₂ （1） to yield CF₂C1CFClCF₂CC1₃ （3）. FCCl₂CFC1CF₂CC1₃ （4）, CC1₃CFCICF₂CC1₃ （5） and CC1₃CF₂CO12CC1₃（6）, and with CFC1₂CF₂CFC1₂ （2） to yield CFC1₂CF₂CC1₃ （8）, CC1₃CF₂CC1₃ （9） and CF₂C1CF₂CC1₃ （10） respectively. The stability order of the perhalogroupings toward replacement reactions with aluminum chloride in these compounds was described. Orthogonal designs were used to study the effect of reaction conditions on the yields of products.更多还原