【摘要】 <正> 迸年来,完全由氯化物形成的玻璃正引起人们的广泛关注。为描述这类玻璃的结构,已经提出了无序阴离子堆积模型,但这方面的实验研究尚未见报道。本文由ThCl₄-PbCl₂系统急冷熔盐和40ThCl₄·30PbCl₂·30NaCl（TPN）、40ThCl₄·30KCl·30NaCl（TKN）玻璃的拉曼光谱讨论了以ThCl₄和PbCl₂为基础组分的氯化物玻璃结构。 用Spex-Ramalog谱仪以背散射方式测试了密封在石英管内的ThCl₄-PbCl₂粉末状急冷熔盐和块状玻璃样品的拉曼光谱。激发光为Ar⁺离子激光的5145（?）线。样品制备另见报更多还原

【Abstract】 The Raman spectra of ThCl₄-PbCl₂ salt system, 40ThCl₄·30KCl·30NaCl and 40ThCl₄·30PbCl₂·30NaCl glasses have been investigated. The Raman peaks of the glasses at 280 cm^-1 are attributed to the increase of coordination number of Th⁴⁺ by introducing alkali ions, and the peak at 200cm^-1 is attributed to the breaking of [PbCl₃]_n long chain. The units of Pb²⁺ and Th⁴⁺ are considered existing separately.更多还原