【摘要】 本文分析了Fe³⁺在钠硼酸盐玻璃中的结构状态及它对该系统玻璃结构的影响。认为加入Fe₂O₃后,坡璃中的一部分[BO₄]向[BO₃]转化;这种转变是由于三硼酸盐基团中的一个[BO₄]转变成[BO₃],从而形成硼氧环。更多还原

【Abstract】 The structural slate of Fe³⁺ in the sodium borate glasses and the influence of Fe³⁺ on the glass structure are analyzed. Part of the [BO₄] tetrahedra in the glasses transforms into [BO₃] triangles after adding Fe₂O₃. It is believed that the transformation is due to the transformation of one of [BO₄] in the triborate group into [BO₃], so that a boroxol ring is formed.更多还原