【摘要】 用苯或乙醇为溶剂,在室温下测得了数种o-ClTPP和TPP稀土金属络合物的荧光发射光谱和荧光激发光谱。荧光激发光谱与相应吸收光谱相对应。除Y（Ⅲ）和Lu（Ⅲ）络合物的荧光量子产率稍大外,其它Ln（Ⅲ）络合物的荧光量子产率都在10^-4数量级。o-ClTPP系列络合物的荧光量子产率不小于TPP系列相应的稀土金属络合物。不同络合物的自然辐射寿命差别不显著。更多还原

【Abstract】 Room temperature fluorescence emission and excitation spectra of rare earth metallocomplexes of o-ClTPP and TPP have been measured. The fluorescence excitation spectra are basically equivalent to the corresponding absorption spectra. The values of fluorescence quantum yield （φ_f） of all the Ln （Ⅲ） complexes are 10^-4 in order of magnitude except the Lu （Ⅲ） and Y （Ⅲ）complexes which have somewhat higher values of φ_f. We have found that the φ_f values of o-ClTPP complexes are not lower than that of the corresponding TPP complexes. The natural radiative lifetimes of different complexes do not differ significantly.更多还原