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用负载型钛系催化剂进行乙烯-丁二烯共聚合的研究(Ⅱ)——聚合条件对共聚反应的影响

Studies on the Copolymerization of Etnylene and Butadiene with Supported Titanium Catalyst (Ⅱ)——The Influences of Reaction Conditions on the CopolymerizationStudies on the Copolymerization of Etnylene and Butadiene with Supported Titanium Catal

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【Author】 Sun Lixin, Lu Zejian, Lu Yun and Lin Shang’an (Institute of Polymer Science, Zhangshan University,Guangzhou)Sun Lixin, Lu Zejian, Lu Yun and Lin Shang’an (Institute of Polymer Science, Zhangshan University,Guangzhou)

【机构】中山大学高分子研究所；中山大学高分子研究所；

【摘要】考察了在TiCl₄/MgCl₂/AlEt₃催化体系下,聚合温度、Al/Ti比、催化剂浓度及溶剂等对乙烯-丁二烯共聚合的影响。更多还原

【Abstract】 In this paper,the influences of reaction conditions including polymerization temperature,Al/Ti ratio,catalyst concentration and solvents varieties on the catalytic efficiency,kinetics of copolymerization,as well as the microstructure,thermal behaviors and viscosity of the resulting copolymerization products were investigated.In this paper,the influences of reaction conditions including polymerization temperature,Al/Ti ratio,catalyst concentration and solvents varieties on the catalytic efficiency,kinetics of copolymerization,as well as the microstructure,thermal behaviors and viscosity of the resulting copolymerization products were investigated.更多还原

【关键词】负载型；聚合条件；催化效率；共聚产物；比浓粘度；活性中心；聚合动力学；聚合温度；聚合物层；链转移剂；

【文献出处】高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,1986年09期

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