节点文献
卤代苯甲酰二茂铁及其还原产物——相应醇的研究
The Study on Halogen Substituted Benzoylferrocenes and Their Reduction Products——Corresponding Alcohols
【摘要】 用二茂铁和卤代苯甲酰氯通过付-克反应合成了十二个邻、间、对的卤代苯甲酰二茂铁,用LiAlH4或KBH4还原可得相应的卤代苯甲酰二茂铁的醇。其中有十六个是新化合物,并对它们的IR和1H NMR谱的性质进行了初步的讨论。
【Abstract】 All of the o,m,p-halogen substituted benzoylferrocenes have been prepared from ferrocene and halogen substituted benzoylchloride by Frieded-Crafts acylation.The ketenes were reduced to the corresponding halogen substituted phenylferrocenyl-methanols with LiAlH4 or KBH4 Sixteen of them are new compounde.The sythesis results and characteristics of IR and 1H NMR spectra of all the above mentioned compounds were preliminarily discussion.
【基金】 中国科学院科学基金
- 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,1986年07期
- 【被引频次】5
- 【下载频次】81