【摘要】 一种新型的第五配位基为叔胺的尾式卟啉铁(间——(邻-（4-二乙胺基丁酰胺基（苯基）三苯基卟啉合铁（Ⅱ）,meso-MDBPTPPFe（Ⅱ））同CO反应生成配合物,用分光光度法测定了配合物的平衡常数,解释了可见紫外光谱的位移现象,用红外差谱方法测得CO的伸缩振动频率是1961cm^-1。更多还原

【Abstract】 The carbon monoxide adduct of Fe complex of meso-mono[o-(4-dietheyla-mino) butyramidophenyl] triphenylporphyrin (tailed porphyrin, meso-MDBPTPP) is reported. The equilibrium constant of the adduct was measured by spectrophoto-metric method and the CO vibration was obtained by using differential spectrum technique. Experimental results demonstrate that the fifth ligand affects the equilibrium constant dramatically.更多还原