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中药白头翁的皂苷研究——分离和主成份结构初步测定
STUDY ON THE SAPONINS OF CHINESE MEDICINAL HERB PULSATILIA CHINENSIS REGEL——ISOLATION AND PRIMARY STUCTURE DETERMINATIONS OF ITS MAIN CONSTITUENTS
【摘要】 分别从白头翁乙酸乙酯及正丁醇提取物得到主皂苷A3和B4.经色层分析、波谱(红外和氢核 磁谱)和化学方法初步证明B4为3-0-[鼠李糖和阿拉伯糖]-28-0-葡萄糖(可能尚含鼠李糖) 3β,23-二羟基-20(29)-羽扇豆烯-28-酸;而A3可能为具有与B4在C—3接有类同糖链结构的3-0- 单链苷。
【Abstract】 Two main saponins A3 and B4 were isolated from the chinese medicnial herb, Pulsatilla chinensis regel(bai-tou-weng), by extraction with ethyl ace- tate and n-butanol respectively. B. is a bisdemoside and its structure prima- rily established as 3-0-[rhamnosyl and arabinosyl]-28-0-glucoside (and pos- sibly with an additional rhamnosyl unit)of 3β, 23-dihydroxy lup-20(29)-en- 28-oic acid by spectra1 data" and chemical method. A3 is a 3-0-monodemoside, probably possessing the same sugar chain structure as B4 on that position.
- 【文献出处】 福州大学学报(自然科学版) ,Journal of Fuzhou University(Natural Sciences Edtion) , 编辑部邮箱 ,1986年01期
- 【被引频次】5
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