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砷、磷、硅的低层析分离及微量砷钇矿的系统分析
Paper Chromatographic Separation of As, P and Si and Analysis of Chernovite in Micro Amount
【摘要】 <正> 砷钇矿是一种罕见的稀土砷酸盐矿物。与氟碳钙钇矿,磷钇矿、钍石、铌铁矿等共生。其分子式为Y(AsO4)。在系统分析中主要测定TR2O3,As2O3,SiO2,P2O8,Fe2O3,CaO,MgO,Al2O3,V2O5,ThO2,U3O8,MnO等成份。砷钇矿的研究对成矿条件,稀土和砷的地球化学研究都是很有意义的。
【Abstract】 In order to separate As, P and Si one an other, in practical analysis paper chromatographic method was used. A developer butyl acetone: methy isobutyl acetone:hydrofluoric acid:nitric aeid=10:10:4:1 was selected. The R_f values were 0.75, 0.4 and zero for As, P and Si respectively.Si, Al and V were separated from other elements with butyl acetone:methyl iso-butyl acetone: nitric acid: water=12.5: 12.5: 2.5: 1.25 as chromatographic reagent, the R_f values of Si, Al and V all were zero. The analytical data were reported.
- 【文献出处】 岩石矿物及测试 , 编辑部邮箱 ,1985年01期
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