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铀—水杨基萤光酮—Zeph—OP四元络合物分光光度反应及其应用
Spectrophotometric Determination of Quarternary Complex of Uranium with Salicylfluorone-zephiramine-emukification-OP
【摘要】 <正> 水杨基萤光酮(SAF)可以作用于铀酰离子(UO2+)生成有色的二元络合物,其灵敏度甚低(ε545=2.3×104)且在水相中不稳定。本文比较了阳离子表面活性剂CTMAB、CPB、Zeph和非离子表面话性剂——乳化剂OP,在微酸性(pH5)介质中对这个二
【Abstract】 A method is developed for the determination of microamounts of U in aqueous solution by U-salicylfluorone-zeph-OP system. The absorption peak of the quarternary complex appears at 555 nm (ε=1.75×10~5). The color of the complex develops quickly stable for more than 5 hours. The method is suitable for determining U heigher than 0.000x% in geological samples.
- 【文献出处】 岩石矿物及测试 , 编辑部邮箱 ,1985年01期
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