节点文献
高分子泥浆处理剂耐盐性的研究(Ⅱ) 盐对处理剂在粘土上吸附性能的影响
STUDY ON THE SALT RESISTANCE OF POLYELECTROLYTE USED AS TREATING AGENT OF DRILLING MUD(Ⅱ)—THE EFFECT OF SALT ON THE ADSORPTION PROPERTY OF THE POLYELECTROLYTE ON CLAY
【摘要】 本文采用紫外光谱法测定浓度,研究SPU(Ⅱ)在安丘标准土上的吸附行为。表明它在粘土上以分子的少数的吸附点吸附,吸附量比常用处理剂大,并且很大程度地受溶液中外加盐的种类和浓度所影响。X光谱分析表明SPU(Ⅱ)在安丘标准土上基本没有层间吸附发生。认为SPU(Ⅱ)中的—SO3-基团是在土粒的外围飘在溶液中,提高土粒的电动电位,并且充分水化而对粘土起保护作用。这是SPU(Ⅱ)具有良好耐盐性的另一个原因。
【Abstract】 The investigation on the adsorption property of SPU (Ⅱ) on Anqiu clay using UV spectrophotometer showed that it was adsorbed onto the clay particles with a few adsorption sites, and that its adsorption quantity was much larger than that of ordinary stabilizing agents and was affected largerly by the concentration of the added salts. The X-ray diffraction showed that no adsorption between layers of the clayd oceured. According to the data of zeta potential, it was suppose the -SO3- of SPU (Ⅱ) situated outside the clay particles leading to the enhancement of the zeta potential and the hydration of the clay particles. This was another reason why SPU (Ⅱ) was a good salt-resistant treating agent for thedrilling muds.
- 【文献出处】 油田化学 ,Oilfield Chemistry , 编辑部邮箱 ,1985年03期
- 【被引频次】2
- 【下载频次】60