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高分子泥浆处理剂耐盐性的研究(Ⅱ) 盐对处理剂在粘土上吸附性能的影响

STUDY ON THE SALT RESISTANCE OF POLYELECTROLYTE USED AS TREATING AGENT OF DRILLING MUD(Ⅱ)—THE EFFECT OF SALT ON THE ADSORPTION PROPERTY OF THE POLYELECTROLYTE ON CLAY

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【作者】 李卓美; 张雪馨; 吕泓;

【Author】 Li Zhuomei Zhang Xunnix Lu Hong (Institute of Polymer science, Zhongshan university, Guangzhou)

【机构】 中山大学高分子研究; 中山大学高分子研究;

【摘要】 本文采用紫外光谱法测定浓度,研究SPU(Ⅱ)在安丘标准土上的吸附行为。表明它在粘土上以分子的少数的吸附点吸附,吸附量比常用处理剂大,并且很大程度地受溶液中外加盐的种类和浓度所影响。X光谱分析表明SPU(Ⅱ)在安丘标准土上基本没有层间吸附发生。认为SPU(Ⅱ)中的—SO3-基团是在土粒的外围飘在溶液中,提高土粒的电动电位,并且充分水化而对粘土起保护作用。这是SPU(Ⅱ)具有良好耐盐性的另一个原因。

【Abstract】 The investigation on the adsorption property of SPU (Ⅱ) on Anqiu clay using UV spectrophotometer showed that it was adsorbed onto the clay particles with a few adsorption sites, and that its adsorption quantity was much larger than that of ordinary stabilizing agents and was affected largerly by the concentration of the added salts. The X-ray diffraction showed that no adsorption between layers of the clayd oceured. According to the data of zeta potential, it was suppose the -SO3- of SPU (Ⅱ) situated outside the clay particles leading to the enhancement of the zeta potential and the hydration of the clay particles. This was another reason why SPU (Ⅱ) was a good salt-resistant treating agent for thedrilling muds.

  • 【文献出处】 油田化学 ,Oilfield Chemistry , 编辑部邮箱 ,1985年03期
  • 【被引频次】2
  • 【下载频次】60
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