【摘要】 本文报道了连续二氧化碳激光敏化CFHCl₂,CFHCI₂+O₂和CFHCl₂+Cl₂的反应,分析了反应产物并讨论了反应机制。利用激光敏化反应,在气相中可以产生CFCl卡宾,此外,在激光敏化氧化和氯化CFHCl₂和CF₂HCl[1]中,反应产物CFClO,CF₂O,CFCl₃a和CF₂Cl₂的产率几乎定量。更多还原

【Abstract】 This paper reports the CW-CO₂ laser sensitized CFHCl₂,CFHCl₂+O₂ andCFHCl₂+Cl₂ reactions,the analysis of the products,and discusses the mechanisms ofthese reactions.It is found that,CFCl carbene can be produced by laser sensitized method,and theyields of CFClO,CF₂O,CFCl₃ and CF₂Cl₂ obtained by laser sensitized oxidation andchlorination of CFHCl₂ and CF₂HCl^[1] are nearly quantitative.更多还原