【摘要】 传统的粉末压片样品严重影响了正电子湮没寿命谱及电子显微镜测量的准确性和重复性。本文克服了以上困难,制出大片非晶离子导体样品,得到了晶化过程正电子湮没寿命谱及扫描电子显微镜研究的新结果。 非晶离子导体B₂O₃-0.7Li₂O-0.7LiCl-xAl₂O₃的实验结果发现:Al₂O₃组分不同对非晶态样品在室温下的正电子平均寿命无较大影响。完全晶化后,正电子平均寿命均有很大降低。而在晶化过程初期,对x=0.15的样品,正电子平均寿命有显著的反常增高,它与电导率的反常增高发生在同一温度范围内。更多还原

【Abstract】 The traditional pressed powder-samples spoil seriously the accuracy and reproduci-bility in measurement of positron lifetime spectra and scanning electron microscopy. This paper has overcome the above difficulties by preparing large amorphous disk-samples, and obtained new result of positron lifetime spectra and scanning electron microscopy during the crystallization process.According to our experiements on amorphous ionic conductor B2O3-0.7Li2O-0.7LiCl-xA12O3, we find that the mean lifetime of positron at room temparature is not affected by content Nariation of A12O3, mean lifetime of positron decreases greatly after full crystallization. Moreover, during the beginning of the crystallization process mean lifetime of positron of sample of x=0.15 exhibits a notable anomalous enhancement, which occurs within the same temperature range while the anomalous enhancement of ionic conductivity appears.更多还原