【摘要】 测量了80A的Fe₃O₄颗粒和三种不同有机物包裹后的Mossbauer谱;不同有机物包裹后Mossbauer谱表现出不同程度的弥散,施加8kOe外磁场以后,所有样品的超顺磁谱均消失,并呈现六线谱。可以用有机物对Fe₃O₄表面Fe离子自旋产生钉扎作用来解释这些实验事实;从施加磁场前后Mossbauer谱的变化对钉扎作用的深度进行了估算。更多还原

【Abstract】 The Mossbauer spectra of 80 (?) magnetite particles before and after coating with the three different organic surfactants were measured. The Mossbauer spectra after coating appear as dispersion to a different degree with the different organism. When magnetic field (8 kOe) was applied, the superparamagnetic spectra for all sample disappeared and the spectra appeared as sextets. The experimental results showed that the organism produce pinning of the spin of the iron ions on the magnetite particle surface. The depth of pinning with and without applied magnetic field were calculated.更多还原