节点文献
由异丁醛氨化制备异丁腈的研究
Preparation of isobutyronitrile by ammonolysis of isobutyraldehyde
【摘要】 以ZnO-Al2O3为催化剂,探讨了各种因素对反应结果的影响,提出了适宜的反应条件:ZnO-Al2O3催化剂中含Al2O340%,常压,反应温度450—475℃,空速1000—2000小时-1,氨醛比1.3:1(摩尔比)。异丁腈收率达91%以上。经精制,异丁腈的纯度达98%以上。
【Abstract】 Factors influencing the results of the reaction were investigated.The suitable reaction conditions were:ZnO-40% Al2O3;atmospheric pressure;reaction temperature,450—475℃;space velosity,1500—2000hr-1;ammonia/isobutyraldehyde mol ratio,1.3:1.The yield of isobutyronitrile was higher than 91% under the above conditions. After distillation, the purity of isobutyronitrile was higher than 98%.
- 【文献出处】 石油化工 ,Petrochemical Technology , 编辑部邮箱 ,1985年12期
- 【被引频次】1
- 【下载频次】135