【摘要】 本文研究了抚顺、茂名油页岩,辽河、泌阳生油岩的热解平行反应模型,以及美国科罗拉多油页岩热解的平行连续反应模型。利用随机试验法等数值计算方法求得了模型中的表观活化能和视频率因子等动力学参数。由这些模型求得的热解生烃率与实验值能较好地吻合。更多还原

【Abstract】 In this paper parallel, pyrolysis models for Fushun and Maoming oil shales and for Liaohe and Biyang source rocks were investigated. Parallel and consecutive reaction model for Colorado oil shale was also studied. The kinetic parameters in the models, including pseudo activation energy and apparent frequency factor were obtained by using Monte Carlo numerical calculation method. The calculated hydrocarbon evolution values are well fitted to the ex-perimental data.更多还原