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南海第氏肉芝软珊瑚化学成分的研究 Ⅱ.Sarcophinone结构的测定

STUDIES ON THE CHEMICAL CONSTITUENTS OF SARCOPHYTON DECARYI FROM THE SOUTH CHINA SEA Ⅱ . THE STRUCTURAL DETERMINATION OF SARCOPHINONE

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【Author】 Yan Zhongyu Chen Chuanqiong (South China Sea Institute of Oceanology, Academia Sinica)Zeng Longmei (Department of Chemistry, Zhongshan University)

【机构】中国科学院南海海洋研究所；中山大学化学系；

【摘要】 <正>前文已经报道了从南海第氏肉芝软珊瑚（Sarcophyton decaryi）中分离到四种化合物的结构,本文报道化合物S₃₀₃的结构测定。 S₃₀₃为新化合物,定名为Sarcophinone,结构式如（Ⅰ）式所示。Sarcophinone为白色棒状结晶,熔点141—142℃,分子式C₂₀H₂₈O₃（高分辨质谱M⁺316.2025）。更多还原

【Abstract】 The compound S303 isolated from the soft corals arcophyton decaryi,C20 H28O3, m.p. 141-142癈, has been designated as "sarcophinone" and is shown to have a structure as expressed by equation ( I ). Its chemical structure has been determined by MS, 1HNMR, 13CNMR and IR spectra, and then confirmed by X-ray diffraction analyses. The precursor of this sarco-phinone may probably be a sarcophine.更多还原

【关键词】肉芝； Sarcophinone；化学成分；碎片峰；红外光谱；石油醚；高分辨质谱；生物活性；内标；西松；

【文献出处】热带海洋 ,Tropic Oceanology , 编辑部邮箱 ,1985年01期

【被引频次】6
【下载频次】43

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