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二氯一氟甲烷多光子解离浓集氘的参数影响

Some Parametric Effects on Laser Enrichment Deuterium by IRMPD of Dichlorofluoromethane

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【作者】 张临阳; 袁鹏; 张允武; 盛六四; 徐帼英; 陆庆正; 刘玉申; 高建谧;

【Author】 Zhang Linyang Yuan Peng Zhang Yunwu Sheng Liusi Xu Gouying Lu Qingzhen Liu Yushen Gao Jianmi(Modern Chemistry Departmeut, University of Science and Technology of China)

【机构】 中国科技大学近代化学系; 中国科技大学近代化学系;

【摘要】 本文使用自制TEACO2激光器研究了二氯一氟甲烷多光子解离浓集氘时,诸如激光波长、脉冲能量、能流密度,氘化组分的压力等参数的影响,并指出了影响过程的可能机理。

【Abstract】 In previous paper[1] We reported that dichlorofluoromethane is a promising compound for laser enrichment deuterium. In this work soma parametric effects(such as wavelength, fluence, total and partial pressure of deuterium compound)were measured experimentally and the quantum yield was calculated from experimental data. We have found the dissociation rate of CFDCl2 is rather dependent on total pressure than on partial pressure of CFDCl2 Whereas the enrichment factor does not depend on Ptotal but strongly on PCFDCl2· A critical pressure of PCFDCl2 was found, above which the reaction is nonisotopic selective The possible mechanism of nonselective reaction was discussed.

  • 【文献出处】 量子电子学 ,Chinese Journal of Quantum Electronics , 编辑部邮箱 ,1985年02期
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