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在分子束中SF6分子单频和双频红外多光子离解谱

Single and Two Frequency IR Multiple-Photon Dissociation of SF6 in Molecular Beam

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【作者】 E.Borsella; R.Fantoni; M.Nardelli; 刘玉申;

【Author】 B.Borsella R. Fantoni M.Nardelli Liu Yushen(Laboratory of Laser Chemistry, Science and Technology University of China, Hefei) Permanant address: ENEA.D.P. TIB Division Fisica Applicata, C.P.65-0004 Frascati, Rome, Italy.

【机构】 ENEA.D.P.TIB.Division Fisica Applicata; C.P.65-00044 Frascati; Rome; Italy; 中国科技大学近代化学系激光化学研究室;

【摘要】 在分子束中做了SF6分子的单频和双频红外多光子离解(MPD)谱,研究了分子转振温度和激光能流对MPD的影响。把实验结果和理论计算结果做了比较分析,认为双光子和叁光子共振跃迁统治了这些离解谱的结构。

【Abstract】 Single and two frequency IR multiple-photon "dissociation (MPD) of SF6 have been performed under molecular beam conditions.The dependence of MFD on CO2 laser fluence and on SFs R-V tem-perature has been studied respectively. The experimental results were compared with that of theoretical calculation, and from which a conclusion that two and three-photon resonance transitions play a dominant role in SF6 MPD spectra was deduced.

  • 【文献出处】 量子电子学 ,Chinese Journal of Quantum Electronics , 编辑部邮箱 ,1985年02期
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