【摘要】 合成了一种新的尾式卟啉铁氯化间一[邻-（4-二乙胺基丁酰胺基）苯基]三苯基卟啉合铁（Ⅲ）（简称meso-MDBPTPPFe（Ⅲ）CI）。用分光光度法研究了meso-MDBPTPPFe（Ⅲ）CI的氧化还原性质及中心离子铁分别为二价和三价时与NO,C0,O₂等双原子小分子及与咪唑、吡啶、二乙胺等有机碱的加合作用。更多还原

【Abstract】 A new tailed porphyriniron complex, meso-mono-[o-（4-dietheylamino） butyramidophenyl] triphenylporphyriniron（ Ⅲ） chloride, meso-MDBPTPPFe（Ⅲ）Cl, was prepared. The formation of the complex was followed by eletronic spectrum. Infrared spectrum exhibits ν_Fe-N and ν_Fe-Cl bands at 355 and 365cm^-1 respectively, and 1001cm^-1 peak attributable to the porphyrin ring’s vibration. EPR spectrum demonstrates that meso-MDBPTPPFe（Ⅲ）Cl is high spin complex with a s= 5/2 ground state. Adducts of both Fe（Ⅱ） and Fe（Ⅲ）complex with diatomic molecules and organic bases were sudied by spectroscopic methhod.更多还原