【摘要】 本文报导了利用陆森黑盐阴离子的相应几何参数和力常数,对网兜骨架[Fe₄S₃]的简正坐标分析,得到了该骨架振动的理论计算频率。以此为根据,针对陆森黑盐系统中的氨合成过程,论证了[Fe₄S₃]网兜骨架一直是存在的,并起着主要固氮作用。更多还原

【Abstract】 The theoretical vibration frequences of the string bag skeleton [Fe4S3] were obtained from a normal coordinate analysis on [fe4S3] skeleton by using a set of corresponding grometrical parameters and forc(?) constants of the black Roussinate anions. On this basis we are able to verify that during the synthesis of NH3in black Roussinate system,the string bag skeleton [fe4S3] exists all the time and plays an important part in the fixation of nitrogen.更多还原