【摘要】 本文提出单核配合物溶液配位体亲核体系分光光度数■的一般处理。本法可由已知稳定常数的配合物,测定未知配合物的稳定常数、溶液组成和摩尔吸光系数;数据处理是直线外推,可见不可见光区都适用,(?)也可自由选择,接续配合物的数目不受限制。选择了β_i较小β_j较大(硫代硫酸锌-EDTA)和β_i较大β_j较小(氟化铁-草酸铁)二体系进行了试验。本文提出的方法将为分光光度法研究配合物溶液提供一个新途径。更多还原

【Abstract】 An improved data processing method for the coordination nucleophilic substitution reaction between two kinds of ligands of mononuclear complexes by spectrophotometrio method has been proposed. This processing method can be applied to the visible and ultraviolet regions of MZ_i and ML_j.Experimental data measured by UV spectrophotometric method for the competition system was as follows:ZnY^2- β₁=1.63×10⁷ ε₁=2.21×10⁵（212 nm）FeC₂O₄⁺ β₁=2×10³ ε₁=2.5×10⁴ （216 nm）Fe （C₂O₄）₂^- β₂=4.5×10⁷ ε₂=5.4×10⁴（216 nm）更多还原