【摘要】 本文研究了在[HCl]>3M介质条件下RuCl₆^2-的稳定性,它能被>5％TNA-煤油液溶定量萃取。用斜率法求得萃合物组成为[（R₃NH）₂RuCl₆]。同时研究了[TNA+N₁₉₂₃]、（TNA+DNA）、（TNA+ALQ）或（TNA+MIBK）对RuCl₆^2-的协萃效应并着重研究了（TNA+DNA）的协萃机理。在[HCl]>3M条件下,用等摩尔系列法求可能的萃合物为[（R₃NH）（R₂NH₂）₃Ru₂Cl₁₂]。协萃系数S=1.4。更多还原

【Abstract】 In this paper both the stability of RuCl6 2- ion in HC1 media and the solvent extraction mechanism of RuCl6 2- extracted with >5% trinonylamine ( TNA ) -kerosine from an aqueous phase of [HC1] > 3M are studied.It is found that the composition of the extracted adduct is [(R3NH)2RuCl8] by the usual slope method.The synergistic extraction effects of RuCl82-are observed in thse systems: with(TNA + N1923) , CTNA+DNA), CTNA+ALQ)and (TNA + MIBK) . The compositionof the adduct from synergistic extraction of (TNA+DNA) in 3M HC1 is postulated as [(R3N H)(R2NH2)3 Ru2Cl12] by the method of isomolar series. The synergistic extraction coefficient of the synergistic reaction is found to be S=1.4.更多还原