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热致液晶性聚合物——含萘环主成分为对羟基苯甲酸的全芳香族共聚酯
THERMOTROPIC LIQUID CRYSTAL POLYMERS——Wholly Aromatic p-Hydroxybenzoic Acid Copolyesters Containing Naphthalene Rings
【摘要】 由对乙酰氧基苯甲酸、对苯二酚二乙酯、2,6-萘二甲酸及间苯二甲酸四种单体通过熔融缩聚反应,合成了全芳香族四组分共聚酯。在一定的组成范围内,共聚酯熔体有很好的液晶性。本文重点讨论了聚合物的组成与性质的关系,热谱特征和液晶相行为。
【Abstract】 The wholly aromatic four-component copolyesters were prepared from p-acetoxy-benzoic acid, hydroquinone diacetate, 2,6-naphthalene dicarboxylic acid and isophthalic acid by melting polycondensation. The melted copolyesters exhibit good liquid crystal-linity in some range of the copolyester compositions.The relationship of composition and properties, DSC thermogram characters and mesomorphic behavior were discussed.
- 【文献出处】 高分子通讯 , 编辑部邮箱 ,1985年04期
- 【被引频次】4
- 【下载频次】74