【摘要】 本文用对甲氧基苯甲醛和吡咯在丙酸中反应制得α、β、γ、δ-四对甲氧基苯基卟啉（p-CH₃O）TPP.它与稀土乙酰丙酮络合物Ln（acac）₃·3H₂O在1,2,4-三氯苯中反应制得镧系乙酰丙酮-α、β、γ、δ-四对甲氧基苯基卟啉络合物Ln（p-CH₃O）TPPacac,并简要地讨论了此类络合物的性质.更多还原

【Abstract】 Tetra- （para-methoxyphenyl） porphyrin （p-CH₃O） TPP was prepared by reaction of para-methoxybenzaldehyde with pyrrole in propionic acid. Lanthanide acetylacetonate -α、 β、 γ、 δ-tetra-（para-methoxyphenyl）-porphyrin complexes Ln （p-CH₃O）TPPacac （Ln:Tb, Dy,Ho, Er, Tm, Yb, Lu;TPP:tetraphenyl-porphyrin） were prepared by direct reaction of （p-CH₃O）TPP with Ln（acac）. 3H₂O in 1, 2, 4-tricolorobenzene. Infrared, UV-Visible spectra and thermal stability of complexes were discussed.更多还原