【摘要】 <正> 作者曾测定水合双邻羟基苄胺铜（Ⅱ）（[Cu（（?）-OC₆H₄CH₂NH₂）·H₂O]·0.5H₂O）的单晶结构,得知铜（Ⅱ）周围形成畸变四方锥型的五配位多面体.由于铜（Ⅱ）的d⁹电子构型对其立体化学有重大影响,其周围配位原子可形成多种具有不同构型、不同数目的配更多还原

【Abstract】 Brown crystals of Cu （o-OC₆H₄CH₂NH₂）₂ were obtained by slow evaporation of an alcoholic solution. The crystal structure was determined on a Enraf-Nonius CAD4 four-circle diffractometer. The space group is P2₁/n, with a=5.395（1）, b=9.007（1）, c=13.421（1）A, β=98.35°, Z=2. The coordinates of all non-H atoms were revealed by Patterson funtion and direct method. Refinement was carried out by the full-matrix least-squares procedure. H atoms were placed in calculated positions and located from difference Fourier syntheses. The structure was refined to a final R value of 0.033. The investigation confirms that Cu（Ⅱ） ion is at a position of symmetry center and is coordinated by 2N, 20 in a square-planar with slight deviation. Two benzene rings are parallel each other and stepped with the plane where coordinated atoms locate. The coordination units are bonded one another via hydrogen bonds and Van der Waals forces.更多还原