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氟硼酸根电极直接电位法测定岩矿中的微量硼

DIRECT [BFJ-ELECTRODE POTENTIAL DETERMINATION OF TRACE BORON IN ROCK SAMPLES

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【作者】 高思登; 李乙雨;

【Author】 Gao Sideng Li Yiyu (Institute of Geochemistry, Academia Sinica)

【机构】 中国科学院地球化学研究所; 中国科学院地球化学研究所;

【摘要】 <正> 硼是典型的亲石元素,在地壳中富集。在岩浆活动中,它是挥发性成分,对矿物结晶及成矿元素的运移和富集有重要影响,测定岩矿中硼的含量不仅可作为划分岩石类型的重要依据,也是判断成矿可能性的依据之一。过去由于受硼测试方法的限制,硼的地球化学研究工作受到一定的影响。

【Abstract】 Described in this paper are the optimum condition for direct [BF4]-electrode pote-ntial determination of trace boron in rocks and the separation and elimination of inter-ferring elements. In addition, the determination of sample standards and experiments an the recovery of sample standard+boron standard have been conducted. On these bases the procedure of determining trace boron in rocks has been established, as is des-cribed in the present paper. Repeated tests have shown that this method is reliable with a detection range of 0.000 X-X%. This method has the advantages of simplicity, stability, high accuracy and low cost.

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