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单元两相气液包裹体热力学方程的推导和应用

DEDUCTION AND APPLICATION OF THE THERMODY-NAMICAL EQUATIONS FOR UNITARY TWO-PHASE FLUID INCLUSIONS

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【作者】 刘斌;

【Author】 Liu Bin (Xi’an Institute of Geology and Mineral Resources, Chinese Academy of Geological Sciences)

【机构】 西安地质矿产研究所;

【摘要】 <正> 作为提供成岩成矿作用信息的包裹体,为广大地质工作者所重视。怎样应用包裹体各种数据,正确解释有关地质问题,是包裹体工作者的重要任务之一。本文就单元两相气液包裹体进行了热力学方程的推导,并对实际应用提出一些看法。

【Abstract】 Three thermodynamical equations for unitary two-phase fluid inclusions have been deduced.(1) The thermodynamical equation for mutual transformation between gas and liquid phases in fluid inclusions. The transformation direction from one phase to the other >ca,n be known in terms of the density and filling degree of gas and liquid.(2) The thermodynamical equation for pressure effect on temperature after ho-mogenization of fluid inclusions. The coefficient of P-T variation is directly propor-tional to the filling degree of gas phase and inversely to the density of gas phase and liquid phase. Equations for homogenization, decrepitation and formation temperatures of fluid inclusions can be inferred from this equation.(3) The thermodynamical equation for decrepitation temperatures of fluid inclu-sions. Many factors have effects on the decrepitation temperatures of fluid inclusions. Decrepitation temperature cannot be considered in any case as formation temperature. Thermal and vapor halos produced by decrepitation of minerals of the same kind and the same period from the same locality are worthy of consideration.

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